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501 Great Games
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501 Great Games - Volume One (2001)(Guildhall Leisure Services).iso
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SCI_PROJ
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MEYER.TX_
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MEYER.TX
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1998-06-02
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MEYER'S APPARATUS for calculating molecular weight
The Meyer's Apparatus is a device used to calculate the molecular weight of a substance, by measuring the volume of
displaced air, which will be the same as the volume of the vaporized substance, and knowing the weight of the substance.
The glass container holding the substance to be measured, must be quit fragile in order for it to break in the specially
receptacle when released from the spatula. The fragile glass container can be filled with a syringe and sealed with parafin.
The measurement with a syringe require utmust precision, so that complete accuracy cannot be assumed without the use
of an analytical balance.
The graduate tube should not be set over the end of the escape tube until after the water in the flask has boiled for a
minute or so. This allows trapped air to expell from the tube. The escaping air-gas mixture displaces an equivalent volume
of water from the graduate. The following correction, the volume as measured in the graduate can be used to determine
the molecular weight of the substance.
MW = (g) x (22.4)
_________
V
g = weight of substance in glass container
V = Volume of liter displaced in graduate
MW = Unknown molecular weight
This method of calulating the molecular weight of a substance is not absolutely accurate. Todays modern laboratory use a
mass spectrograph, which can make a greater number of molecular weight measurements in short time. If we take 1 gram
ethly alcohol, CH3CH2OH, which reads a bit less than 0.5 ml of space when vaporized, and apply it to our calulation, we
should get somewhere around 46.07, which is the molecular weight of ethly alcohol. This calculation assumes that the
measurements were take at 0 deg C, at an atmospheric pressure of 760 mm of mercury.